Synthesis, characterization and gas transport properties of novel poly(amine-imide)s containing tetraphenylmethane pendant groups

Journal of Materials Chemistry A Pub Date: 2014-04-04 DOI: 10.1039/C4TA00429A

Abstract

Two bis(amine anhydride) monomers containing tetraphenylmethane pendant groups were synthesized from the palladium-catalyzed amination reaction of N-methyl-4-chlorophthalimide with different arylamines, followed by alkaline hydrolysis of the intermediate bis(amine-imide)s and subsequent dehydration of the resulting tetraacids. These monomers were polymerized with the appropriate aromatic diamines to obtain a series of novel poly(amine-imide)s. The obtained polymers exhibited good solubility in many aprotic solvents and had glass transition temperatures in the range of 310 to 395 °C. Thermogravimetric analysis showed that all of the polymers were stable, with 10% weight loss recorded above 510 °C under nitrogen. The surface areas of these novel poly(amine-imide)s ranged from 78 to 290 m2 g?1. Films obtained by casting exhibited a combination of relatively high permeability and modest to good permselectivity with values close to Robeson’s upper bound limit for O2/N2 and CO2/CH4 gas pairs.

Graphical abstract: Synthesis, characterization and gas transport properties of novel poly(amine-imide)s containing tetraphenylmethane pendant groups
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