Single-component frameworks for heterogeneous catalytic hydrolysis of organophosphorous compounds in pure water?

Chemical Communications Pub Date: 2019-05-16 DOI: 10.1039/C9CC02236H

Abstract

Amine modified Zr6-based metal–organic frameworks (MOFs) were synthesized through solvent-assisted linker incorporation (SALI) and utilized as single-component heterogeneous catalysts for the hydrolysis of organophosphorous compounds under solely aqueous conditions at room temperature. These materials display unprecidentedly fast catalytic hydrolysis for dimethyl p-nitrophenyl phosphate (DMNP) and nerve agent VX without the use of a buffered solution.

Graphical abstract: Single-component frameworks for heterogeneous catalytic hydrolysis of organophosphorous compounds in pure water
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