Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO2?
RSC Advances Pub Date: 2019-10-15 DOI: 10.1039/C9RA05253D
Abstract
An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO2. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides.
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Journal Name:RSC Advances
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CAS no.: 89640-58-4