Active catalysts prepared using a vanadium-containing oligosilsesquioxane for selective photo-assisted oxidation of methane into methanal

Chemical Communications Pub Date: 1900-01-01 DOI: 10.1039/A707173F

Abstract

Catalysts of characteristic pore structure derived from silica-supported vanadium-containing silsesquioxane show excellent activity towards the selective photo-assisted catalytic oxidation of methane into methanal (at 493 K, 139 μmol h–1, TON ca. 9 h–1, selectivity 81%), indicating its potent abilities as an excellent precursor for porous oxide catalysts.

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