Tackling poison and leach: catalysis by dangling thiol–palladium functions within a porous metal–organic solid?
Chemical Communications Pub Date: 2015-02-27 DOI: 10.1039/C5CC00140D
Abstract
Self-standing thiol (?SH) groups within a Zr(IV)-based metal–organic framework (MOF) anchor Pd(II) atoms for catalytic applications: the spatial constraint prevents the thiol groups from sealing off/poisoning the Pd(II) center, while the strong Pd–S bond precludes Pd leaching, enabling multiple cycles of heterogeneous catalysis to be executed.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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