Synthesis of thiol-clickable and block copolypeptide brushes vianickel-mediated surface initiated polymerization of α-amino acid N-carboxyanhydrides (NCAs)??

Chemical Communications Pub Date: 2011-04-19 DOI: 10.1039/C1CC11534K

Abstract

We describe the synthesis of homo-, block, and clickable copolypeptide brushes from low surface area substrates using nickel-mediated surface-initiated polymerization of α-aminoN-carboxyanhydrides.

Graphical abstract: Synthesis of thiol-clickable and block copolypeptide brushes vianickel-mediated surface initiated polymerization of α-amino acid N-carboxyanhydrides (NCAs)
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