Rhodium(iii)-catalyzed C–H allylation of electron-deficient alkenes with allyl acetates?
Chemical Communications Pub Date: 2014-11-05 DOI: 10.1039/C4CC07597H
Abstract
Rhodium-catalyzed C–H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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