Synthesis of perinaphthenones through rhodium-catalyzed dehydrative annulation of 1-naphthoic acids with alkynes?
Organic & Biomolecular Chemistry Pub Date: 2018-10-05 DOI: 10.1039/C8OB01453A
Abstract
An efficient approach to the synthesis of perinaphthenones via the rhodium-catalyzed dehydrative annulation of 1-naphthoic acids with internal alkynes was developed. Norbornadiene can act as an acetylene equivalent to give unsubstituted perinaphthenones at the 2- and 3-positions via dehydrative annulation followed by a retro Diels–Alder reaction.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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