Regioselective allylgallation of terminal alkynes

Chemical Communications Pub Date: 2005-02-09 DOI: 10.1039/B417975G

Abstract

The reactions of terminal alkynes with allylgallium reagents generated in situ from gallium and allyl bromides gave the corresponding 1,4-dienes in good yield via Markovnikov addition in THF at 70 °C.

Graphical abstract: Regioselective allylgallation of terminal alkynes
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