A triple-triangle cluster derived from a simple tridentate ligand?
Dalton Transactions Pub Date: 2019-11-05 DOI: 10.1039/C9DT03232K
Abstract
The heptanuclear ferric cluster, [FeIII7(O)6(HL)5(H2L)(H2O)8](BF4)4 (H2L = 2,6-bis(1,5-diphenyl-1H-pyrazol-3-yl)pyridine), was synthesized by the reaction of the planar tridentate ligand H2L with iron(II) tetrafluoroborate hexahydrate. The cluster has a corner-shared triple-triangle core structure connected by three μ-O atoms, and it has a spin-frustrated ferrimagnetic spin ground state of S = 19/2.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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