Stepwise synthesis and characterization of germa[4], [5], [8], and [10]pericyclynes?
Dalton Transactions Pub Date: 2015-05-19 DOI: 10.1039/C5DT01411E
Abstract
The stepwise syntheses of germa[N]pericyclynes, including [5]pericyclynes, and their characterization are described. The yields of germa[4] and [8]pericyclynes were improved significantly compared to those obtained in previous studies. The routes reported herein afforded the novel germa[5] and [10]pericyclynes, which were characterized by X-ray crystallography, UV-Vis spectroscopy, and fluorescence emission spectroscopy. A unique fluorescence emission was observed for the large germa[10]pericyclyne ring.
![Graphical abstract: Stepwise synthesis and characterization of germa[4], [5], [8], and [10]pericyclynes](http://scimg.chem960.com/usr/1/C5DT01411E.jpg)
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Journal Name：Dalton Transactions
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