A trinuclear Zn3(OAc)4-3,3′-bis(aminoimino)binaphthoxide complex for highly efficient catalytic asymmetric iodolactonization?
Chemical Communications Pub Date: 2014-04-24 DOI: 10.1039/C4CC02415J
Abstract
A 3,3′-bis(aminoimino)BINOL ligand was newly designed and synthesized for the formation of a trinuclear Zn complex upon reaction with Zn(OAc)2. Using the harmony of the tri-zinc atoms, 1 mol% Zn3(OAc)4-3,3′-bis(aminoimino)binaphthoxide catalyzed asymmetric iodolactonization in up to 99.9% ee.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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