Spontaneous resolution in a halogen bonded supramolecular architecture?

Chemical Communications Pub Date: 2005-01-27 DOI: 10.1039/B417771A

Abstract

The halogen bonding driven self-assembly of 1,8-diiodoperfluorooctane and N,N,N′,N′-tetramethyl-p-phenylenediamine induces the formation of a chiral and enantiopure co-crystal wherein the fluorinated chains adopt an unusual gauche arrangement.

Graphical abstract: Spontaneous resolution in a halogen bonded supramolecular architecture
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