Palladium-catalyzed coupling of azoles with 1-aryltriazenes via C–H/C–N cleavage?
Organic Chemistry Frontiers Pub Date: 2017-03-28 DOI: 10.1039/C7QO00174F
Abstract
In the presence of CuCl and ButOLi, PdCl2/dppe catalyzes the reaction of (benzo)oxazoles or (benzo)thiazoles with 1-aryltriazenes to yield arylated products of (benzo)oxazoles or (benzo)thiazoles. Functional groups including F, Cl, CF3, COOEt, CN, OMe, NMe2, Py, and thienyl groups can be tolerated.
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Journal Name：Organic Chemistry Frontiers
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