Palladium-catalysed asymmetric allylic alkylation in the presence of a chiral ‘light fluorous’ phosphine ligand
Chemical Communications Pub Date: 2001-06-14 DOI: 10.1039/B103074B
Abstract
The easily accessible, enantiopure (R)-(+)-2-diarylphosphino-2′-alkoxy-1,1′-binaphthyl 1 bearing three fluorous ponytails is an efficient ligand in the palladium-catalysed asymmetric allylic substitution of 1,3-diphenylprop-2-enyl acetate affording chiral products of up to 87% ee.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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