Sensing the chirality of various organic solvents by helically arranged π-blades?

Chemical Communications Pub Date: 2018-09-10 DOI: 10.1039/C8CC06277C

Abstract

Although the chiral enrichment of dynamic prochiral molecules usually requires a strong interaction with a chiral source, the enantiomer ratio of a propeller-shaped molecule, obtained by a recently developed boron-mediated benzannulation reaction of alkynes, is biased in various organic solvents through solvation for the propeller moieties.

Graphical abstract: Sensing the chirality of various organic solvents by helically arranged π-blades
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