Novel double alkoxides of titanium(IV) and iron(II)/(III): synthetic, structural and spectroscopic studies

New Journal of Chemistry Pub Date: 2002-05-23 DOI: 10.1039/B111517K

Abstract

The first structurally characterised titanium and iron polynuclear isopropoxides [FeCl{Ti2(OPri)9}], 1, and [Ti3(OMe)2(OPri)9][Fe4TiCl4(O)(OPri)9], 2, have been prepared from 2 : 1 : 1 mixtures of [Ti(OPri)4], K(OPri) and FeCl2. Their identity was confirmed by a number of chemical and physical methods including X-ray diffractometry. Semiempirical quantum mechanical calculations were consistent with an S?=?2 ground state for 1. Structural and spectroscopic data support a mixed-valence formulation for the unique {Fe4Ti} anion in 2.

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