Preparation and characterization of bisphenolato magnesium derivatives: an efficient catalyst for the ring-opening polymerization of ε-caprolactone and L-lactide?

Dalton Transactions Pub Date: 2009-10-06 DOI: 10.1039/B912443H

Abstract

A series of magnesium complexes have been prepared and characterized, in which [(EDBP-Me)Mg(μ-OBn)]2 (4) has shown high activity toward the ring-opening polymerization (ROP) of ε-caprolactone and L-lactide. 2,2′-Ethylidene-bis(4,6-di-tert-butylphenol)-monomethyl ether ([EDBP-(Me)H]) is prepared by the reaction of 2,2′-ethylidene-bis(4,6-di-tert-butylphenol) (EDBP-H2) with dimethyl sulfate. The reaction of [EDBP-(Me)H] with nBu2Mg yields [(EDBP-Me)MgnBu]2, which further reacts with benzyl alcohol and N,N-dimethylethylenediamine giving complexes [(EDBP-Me)Mg(μ-OBn)]2 (4) and {[EDBP(Me)]Mg(μ-Me2NCH2CH2NH)}2 (5), respectively. Experimental results indicate that the activity of complex 4 toward cyclic esters is higher than that of [(μ-EDBP)Mg]2/(BnOH).

Graphical abstract: Preparation and characterization of bisphenolato magnesium derivatives: an efficient catalyst for the ring-opening polymerization of ε-caprolactone and L-lactide
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