Modeling of the hydrophobic microenvironment of water-soluble molybdoenzymes in an aqueous micellar solution?
Dalton Transactions Pub Date: 2015-05-29 DOI: 10.1039/C5DT01112D
Abstract
A toluene-soluble molybdenum(VI) complex containing a bulky hydrophobic substituent, (Et4N)2[MoVIO2{1,2-S2-3,6-(RCONH)2C6H2}2] (R = (4-tBuC6H4)3C), was dissolved in the hydrophobic core of a micelle in an aqueous medium and catalyzed the biomimetic reduction of an amine N-oxide by an NADH analog. The kinetic isotope effect of solvent water clearly indicates that water molecules are essential for catalysis and are involved in the rate-determining step.
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Journal Name：Dalton Transactions
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