Palladium-catalyzed silylation reaction between benzylic halides and silylboronate?
Chemical Communications Pub Date: 2016-03-21 DOI: 10.1039/C6CC00713A
Abstract
An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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