Non-covalent tetrel bonding interactions in hemidirectional lead(ii) complexes with nickel(ii)-salen type metalloligands?
New Journal of Chemistry Pub Date: 2018-02-26 DOI: 10.1039/C7NJ05148D
Abstract
Four hetero-dinuclear nickel(II)/lead(II) complexes have been synthesized and characterized. Their structures have been confirmed by single crystal X-ray diffraction studies. In each complex, nickel(II) is placed in the inner N2O2 compartment and lead(II) in the outer O2O2′ compartment of the respective Schiff base. In complexes 1, 3 and 4, lead(II) centres are hemidirectionally coordinated, and thus are well suited for establishing tetrel bonding interactions which have been investigated thoroughly by means of DFT calculations.
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Journal Name：New Journal of Chemistry
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CAS no.: 89640-58-4
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