Metal-free, visible-light photoredox catalysis: transformation of arylmethyl bromides to alcohols and aldehydes?

RSC Advances Pub Date: 2014-09-16 DOI: 10.1039/C4RA09190F

Abstract

A mild, simple, and controllable metal-free photocatalytic system for the transformation of arylmethyl bromides to corresponding alcohols and aldehydes in high yields with visible-light irradiation has been achieved. Eosin Y was found to be an efficient promoter for this oxidative dehalogenation reaction under photo irradiation conditions.

Graphical abstract: Metal-free, visible-light photoredox catalysis: transformation of arylmethyl bromides to alcohols and aldehydes
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