Palladium-catalysed regioselective hydroamination of 1,3-dienes: synthesis of allylic amines?
Organic Chemistry Frontiers Pub Date: 2014-03-18 DOI: 10.1039/C4QO00023D
Abstract
Catalytic hydroamination of unactivated 1,3-dienes represents a sustainable and atom-economic C–N bond forming process. Here, we present a novel catalytic system consisting of Pd(cod)Cl2 in combination with DPEphos for the selective 1,4-hydroamination (anti-Markovnikov reaction) of a series of acyclic and cyclic dienes. The reactions proceed in good yields and allow for the exclusive formation of allylic amines with high regioselectivity and do not need any additives.
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Journal Name：Organic Chemistry Frontiers
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