Low-cost instant CO generation at room temperature using formic acid, mesyl chloride and triethylamine?
Reaction Chemistry & Engineering Pub Date: 2016-02-15 DOI: 10.1039/C6RE00006A
Abstract
Three low-cost standard lab chemicals, formic acid, mesyl chloride and triethylamine, were used for instant carbon monoxide (CO) generation at room temperature. Subsequently this gas was implemented in palladium-catalysed aminocarbonylation chemistry. Moreover, 13C-enriched formic acid was used as one of the most economical CO precursors for 13C-carbonyl labelling.
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Journal Name：Reaction Chemistry & Engineering
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CAS no.: 89640-58-4
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