Palladium-catalyzed aerobic oxidative allylic C–H arylation of alkenes with polyfluorobenzenes?

Chemical Communications Pub Date: 2014-04-16 DOI: 10.1039/C4CC02023E

Abstract

An aerobic oxidative cross-coupling reaction of alkenes with polyfluorobenzenes, through palladium-catalyzed allylic C–H activation, is reported. This attractive route provides a new way to forge allylic C–C bonds of valuable products, in good yields, with high regioselectivity.

Graphical abstract: Palladium-catalyzed aerobic oxidative allylic C–H arylation of alkenes with polyfluorobenzenes
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