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Oxidative alkoxycarbonylation of terminal alkenes with carbazates?

Chemical Communications Pub Date: 2013-05-31 DOI: 10.1039/C3CC42994F

Abstract

A range of terminal alkenes smoothly underwent palladium-catalyzed oxidative alkoxycarbonylation with carbazates under an oxygen atmosphere to afford structurally diverse α,β-unsaturated esters in moderate to good yields with excellent regioselectivity and E selectivity.

Graphical abstract: Oxidative alkoxycarbonylation of terminal alkenes with carbazates

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