New lead(ii) borates in the PbO/PbF2/H3BO3 ternary phase diagram: syntheses and structures of β-Pb6B10O21 and Pb4B8O16?

New Journal of Chemistry Pub Date: 2017-03-29 DOI: 10.1039/C7NJ00203C

Abstract

Through systematic research on the PbO/PbF2/H3BO3 ternary phase diagram, two new lead(II) borates, β-Pb6B10O21 and Pb4B8O16, were synthesized by a high temperature solution method. The polymerization degree of the B–O network was analyzed with increasing B?:?Pb ratio.

Graphical abstract: New lead(ii) borates in the PbO/PbF2/H3BO3 ternary phase diagram: syntheses and structures of β-Pb6B10O21 and Pb4B8O16
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