Nitroxyl radical based conjugated microporous polymers as heterogeneous catalysts for selective aerobic alcohol oxidation?
Journal of Materials Chemistry A Pub Date: 2018-05-05 DOI: 10.1039/C8TA02664E
Abstract
Covalent anchoring of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) on the scaffold of conjugated microporous polymers (CMPs) was achieved via cost-effective FeCl3-catalyzed oxidative polymerization of dicarbazole functionalized TEMPO. These TEMPO-CMPs exhibit excellent catalytic performance for the aerobic oxidation of a wide variety of alcohols under metal-free conditions. In addition, the TEMPO-CMPs could be recycled at least 20 times with good retention of high catalytic activities.
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Journal Name：Journal of Materials Chemistry A
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CAS no.: 89640-58-4
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