New porphyrin derivatives for phosphate anion sensing in both organic and aqueous media? ?
Chemical Communications Pub Date: 2013-11-26 DOI: 10.1039/C3CC47504B
Abstract
New porphyrin-based anion receptors have been prepared from meso-tetrakis(pentafluorophenyl)porphyrin (TPPF20) and diamine derivatives. These receptors (compounds 1–3) interact preferentially with phosphate anions both in organic solutions and in basic aqueous media when coated on gold piezoelectric quartz crystals. A single crystal X-ray structure of the bis-HF complex of a imine derivative of 1 was obtained; it serves to highlight the main interactions between the anion and cation receptors in the solid state.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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