Impact of the synthetic approach on the magnetic properties and homogeneity of mixed crystals of tunable layered ferromagnetic coordination polymers?

Dalton Transactions Pub Date: 2020-11-04 DOI: 10.1039/D0DT03428B

Abstract

Reaction of Co(NCS)2 and Ni(NCS)2 with 4-tert-butylpyridine in ethyl acetate leads to the formation of mixed crystals of a layered compound with the composition [CoxNi1?x(NCS)2(4-tert-butylpyridine]n. The mixed crystal formation was investigated by a combination of atomic absorption spectroscopy, X-ray powder diffraction and IR spectroscopy. Magnetic and specific heat measurements prove dominating ferromagnetic exchange interactions within the layers and a ferromagnetic transition. Depending on the synthetic method, inhomogeneous samples were obtained, for which predominantly the large difference in the solubility of the homometallic compounds might be responsible. Very long reaction time leads to much better samples for which a distinct critical temperature is observed that increases smoothly with increasing Ni content.

Graphical abstract: Impact of the synthetic approach on the magnetic properties and homogeneity of mixed crystals of tunable layered ferromagnetic coordination polymers
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