Iron oxalate capped iron–copper nanomaterial for oxidative transformation of aldehydes?
New Journal of Chemistry Pub Date: 2014-12-01 DOI: 10.1039/C4NJ01966K
Abstract
An efficient, sustainable and green procedure for the synthesis of selective orthorhombic iron(oxalate) capped Fe–Cu bimetallic oxide nanomaterial [Fe(ox)Fe–CuOx] was developed using a sodium borohydride reduction of iron(II) salt in the presence of oxalic acid at room temperature followed by addition of copper sulfate in water. The reported method is a cost-effective chemical route for producing [Fe(ox)Fe–CuOx] nano material at the gram level with a surface area of 78.4 m2 g?1 and a pore volume of 0.141 cm3 g?1. The [Fe(ox)Fe–CuOx] nanomaterials were found to be useful as a recoverable catalyst for the oxidative transformation of an aldehyde to its corresponding ester and acid in presence of hydrogen peroxide.
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Journal Name：New Journal of Chemistry
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CAS no.: 89640-58-4
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