Ionothermal synthesis of a new (4,12)-connected heterometallic iodoplumbate with [Pb4(OH)4] cubane as joint points of the helices?

CrystEngComm Pub Date: 2010-11-12 DOI: 10.1039/C0CE00651C

Abstract

The first ionothermal case of the heterometallic iodoplumbate, [CuPb2I2Br(OH)2] (1), was prepared using 1-ethyl-3-methyl imidazolium bromide as a solvent. It exhibits an unprecedented (4,12)-connected topology with [Pb4(OH)4] cubane as the joint points of the helices.

Graphical abstract: Ionothermal synthesis of a new (4,12)-connected heterometallic iodoplumbate with [Pb4(OH)4] cubane as joint points of the helices
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