Iron catalyzed diastereoselective hydrogenation of chiral imines?
Organic & Biomolecular Chemistry Pub Date: 2017-06-14 DOI: 10.1039/C7OB01123G
Abstract
Cyclopentadienone-based iron complexes were used for the first time to successfully catalyze the diastereoselective hydrogenation of enantiopure imines. Chiral amines, including valuable biologically active products, were obtained often as enantiomerically pure compounds. Computational studies helped to elucidate the chemical and stereochemical aspects of the iron-catalyzed reaction.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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