Glycosylation with glycosyl benzyl phthalates as a new type of glycosyl donor?

Organic & Biomolecular Chemistry Pub Date: 2004-08-04 DOI: 10.1039/B405793G

Abstract

A glucopyranosyl benzyl phthalate, two mannopyranosyl benzyl phthalates, and a 2-deoxyglucopyranosyl benzyl phthalate, which were prepared from the corresponding 1-hydroxy sugars and benzyl hydrogen phthalate, were found to be efficient glycosyl donors in the glycosylations of various glycosyl acceptors using TMSOTf as a promoter.

Graphical abstract: Glycosylation with glycosyl benzyl phthalates as a new type of glycosyl donor
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