High oxidation state bromocarbyne complexes?
Chemical Communications Pub Date: 2016-12-12 DOI: 10.1039/C6CC08946A
Abstract
Bromination of the carbyne complexes [W(![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
CR)Br(CO)2(dcpe)] (R = Ph, SiPh3; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W(CPh)Br3(dcpe)] and [W(CBr)Br3(dcpe)], the latter via an unprecedented bromodesilylation process.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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