Imination reactions of free and coordinated 2-diphenylphosphino-1-phenyl-phospholane: Access to regioisomeric ruthenium(ii) complexes containing novel iminophosphorane–phosphine ligands

New Journal of Chemistry Pub Date: 2006-07-26 DOI: 10.1039/B606781F

Abstract

In this work, selective monoimination reactions of free and Ru-coordinated 2-diphenylphosphino-1-phenyl-phospholane with diphenylphosphoryl azide or 4-azido-2,3,5,6-tetrafluorobenzonitrile are described. Following this approach, a large variety of neutral and cationic mono- and dinuclear (η6-arene)–ruthenium(II) complexes containing regioisomeric iminophosphorane–phosphine ligands could be prepared and, in some cases, structurally characterized by means of X-ray diffraction methods. The catalytic activity of these ruthenium complexes, both in racemic or enantiomerically pure form, in Diels–Alder cycloaddition reactions is also presented.

Graphical abstract: Imination reactions of free and coordinated 2-diphenylphosphino-1-phenyl-phospholane: Access to regioisomeric ruthenium(ii) complexes containing novel iminophosphorane–phosphine ligands
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