A nona-vacant Keggin-type tricarbonyl rhenium derivative {[PMo3O16][Re(CO)3]4}5? and its catalytic performance for CO2 cycloaddition reactions?
RSC Advances Pub Date: 2015-07-31 DOI: 10.1039/C5RA14201F
Abstract
A nona-vacant Keggin-type tricarbonyl rhenium derivative [(NH4)5]{[PMo3O16][Re(CO)3]4}·1.5H2O was obtained and characterized. Its frontier orbitals were computed by density functional theory (DFT) calculations. Furthermore, it could act as a Lewis acid catalyst and promote the conversion of CO2 to cyclic carbonate under mild reaction conditions with pyrrolidinium bromide as a co-catalyst.
![Graphical abstract: A nona-vacant Keggin-type tricarbonyl rhenium derivative {[PMo3O16][Re(CO)3]4}5? and its catalytic performance for CO2 cycloaddition reactions](http://scimg.chem960.com/usr/1/C5RA14201F.jpg)
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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