Hydrothermal synthesis and magnetic behaviour of beta-Li3VF6 and Na3VF6

New Journal of Chemistry Pub Date: 2015-03-25 DOI: 10.1039/C5NJ00284B

Abstract

Fluorides and oxide-fluorides play important roles in several technological fields. Herein, we have synthesized the crystals of β-Li3VF6 and Na3VF6 under mild hydrothermal conditions without any hydrofluoric acid. These two compounds were well-crystallized and showed antiferromagnetic interactions with isolated magnetic units.

Graphical abstract: Hydrothermal synthesis and magnetic behaviour of beta-Li3VF6 and Na3VF6
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