High efficiency thermally activated delayed fluorescence based on 1,3,5-tris(4-(diphenylamino)phenyl)-2,4,6-tricyanobenzene?

Chemical Communications Pub Date: 2015-02-13 DOI: 10.1039/C5CC00511F

Abstract

A trigonal donor–acceptor molecule of 1,3,5-tris(4-(diphenylamino)phenyl)-2,4,6-tricyanobenzene (3DPA3CN) was synthesized to exhibit efficient thermally activated delayed fluorescence. By doping 3DPA3CN into a wide energy gap host, the film had a photoluminescence quantum efficiency of 100% with the reverse intersystem crossing efficiency of 100%. An OLED including the emitter exhibited a very high external quantum efficiency (ηEQE) of 21.4%.

Graphical abstract: High efficiency thermally activated delayed fluorescence based on 1,3,5-tris(4-(diphenylamino)phenyl)-2,4,6-tricyanobenzene
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