Enantiomeric programming in tripodal transition metal scaffolds
New Journal of Chemistry Pub Date: 2007-05-25 DOI: 10.1039/B703761A
Abstract
A new route to the isolation of the enantiopure tris-chelate complex (Δ/Λ)-fac-[Ru(L1)3]2+ (where L1 is 2,2′-bipyridine-5-carboxylic acid) is demonstrated, where the transition metal centre retains the memory of the chirality present in a simple tripodal tether used to control the metal centred geometry.
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Journal Name：New Journal of Chemistry
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CAS no.: 89640-58-4
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