Facile central-element exchange in neutral hexacoordinate germanium and silicon complexes; synthesis and characterization of germanium complexes?

Dalton Transactions Pub Date: 2010-08-18 DOI: 10.1039/C0DT00625D

Abstract

Neutral hexacoordinate germanium complexes with hydrazido chelating ligands have been synthesized and characterized. Facile exchange of central element between silicon and germanium in these complexes is demonstrated, following given selectivity constraints.

Graphical abstract: Facile central-element exchange in neutral hexacoordinate germanium and silicon complexes; synthesis and characterization of germanium complexes
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