Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis?
Chemical Communications Pub Date: 2014-05-21 DOI: 10.1039/C4CC02319F
Abstract
Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P–P*)] (P–P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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