Electrosynthesis of new quinone sulfonimide derivatives using a conventional batch and a new electrolyte-free flow cell?
Green Chemistry Pub Date: 2018-07-26 DOI: 10.1039/C8GC01727A
Abstract
The electrochemical synthesis of some new quinone sulfonimides (QSI) was achieved by the constant current oxidation of 4-aminophenyl ether (APE) in the presence of arylsulfinic acids in both electrochemical conventional batch and flow cells. Compared to the conventional cell, the use of the lab-made electrochemical flow cell has many advantages including no use of a supporting electrolyte, excellent yields and short reaction times. The synthesis led to new products in high purity and yield in a single pass under green conditions.
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Journal Name:Green Chemistry
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CAS no.: 89640-58-4