A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene?
Polymer Chemistry Pub Date: 2021-04-14 DOI: 10.1039/D1PY00191D
Abstract
We have achieved breakthroughs for the efficient synthesis of linear polydicyclopentadiene (pDCPD) via photoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP). Molecular weight control from 1 to 16 kDa can be targeted in a straightforward manner. Assisted by this method, the Tg–Mn dependence of linear pDCPD is investigated and reported for the first time.
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Journal Name：Polymer Chemistry
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CAS no.: 89640-58-4
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