Diversified magnetic behaviors of new nickel(ii) and copper(ii) azido coordination polymers templated by diethyl or triethyl amines?
New Journal of Chemistry Pub Date: 2016-12-22 DOI: 10.1039/C6NJ03268K
Abstract
The reactions of NiII or CuII ions with N3? anions in the presence of templated diethyl or triethyl amines afford three new azido-bridged coordination polymers, namely, [Ni(N3)2(Deeda)] (1), (DeaH)[Cu3(N3)7] (2), and (TeaH)[Cu4(N3)9] (3), where Deeda, (DeaH)+ and (TeaH)+ represent N,N-diethylethane-1,2-diamine, diethylammonium and triethylammonium, respectively. Magnetic studies revealed that they exhibit metamagnetism, spin glass and canted ferromagnetism, respectively, induced by different coordination modes of the azide ligands.
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Journal Name：New Journal of Chemistry
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CAS no.: 89640-58-4
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