A general protocol for the synthesis of Pt-NHC (NHC = N-heterocyclic carbene) hydrosilylation catalysts?
Dalton Transactions Pub Date: 2020-10-09 DOI: 10.1039/D0DT03480K
Abstract
A general, user-friendly synthetic route to [Pt(NHC)(L)Cl2] and [Pt(NHC)(dvtms)] (L = DMS, Py; DMS = dimethyl sulfide, dvtms = divinyltetramethylsiloxane, Py = pyridine) complexes has been developed. The procedure is applicable to a wide range of ligands and enables facile synthetic access to key Pt(0)- and Pt(II)-NHC complexes used in hydrosilylation catalysis.
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Journal Name：Dalton Transactions
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