A heterogeneous layered bifunctional catalyst for the integration of aerobic oxidation and asymmetric C–C bond formation?
Chemical Communications Pub Date: 2013-09-05 DOI: 10.1039/C3CC46204H
Abstract
The design and synthesis of a heterogeneous bifunctional chiral catalyst for the sequential aerobic oxidation–asymmetric Michael reactions between primary allylic alcohols and dibenzyl malonate are described. Interestingly, we found that layering bimetallic nanoparticles over the organocatalyst, within the chiral composite material, is crucial for catalytic activity.
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Journal Name：Chemical Communications
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