13C NMR as a general tool for the assignment of absolute configuration?
Chemical Communications Pub Date: 2010-10-01 DOI: 10.1039/C0CC02774J
Abstract
13C NMR, alone or in combination with 1H NMR, allows the assignment of the absolute configuration of chiral alcohols, amines, carboxylic acids, thiols, cyanohydrins, sec,sec-diols and sec,sec-aminoalcohols, derivatized with appropriate chiral auxiliaries. This extends the assignment possibilities of NMR to fully deuterated and to nonproton containing compounds.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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