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Copper-catalyzed C(sp3)–H functionalization of ketones with vinyl azides: synthesis of substituted-1H-pyrroles?

Organic & Biomolecular Chemistry Pub Date: 2015-09-04 DOI: 10.1039/C5OB01407G

Abstract

Copper-catalyzed C(sp³)–H functionalization of ketones with vinyl azides for the synthesis of substituted pyrroles has been developed. The method is a straightforward and efficient way to access a series of 2,3,5-trisubstituted-1H-pyrroles in modest to excellent yields with broad functional group tolerance under mild conditions.

Graphical abstract: Copper-catalyzed C(sp3)–H functionalization of ketones with vinyl azides: synthesis of substituted-1H-pyrroles

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Organic & Biomolecular Chemistry

Journal Name：Organic & Biomolecular Chemistry

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