Copper-catalyzed O-arylation of N-protected 1,2-aminoalcohols using functionalized trivalent organobismuth reagents?
Organic & Biomolecular Chemistry Pub Date: 2014-12-09 DOI: 10.1039/C4OB02497D
Abstract
The O-arylation of 1,2-aminoalcohols using functionalized triarylbismuth reagents is reported. The reaction can be performed using substoichiometric amounts of copper acetate and operates under mild conditions. Good functional group tolerance is observed, giving access to a range of β-aryloxyamines. The effect provided by the amino group in the arylation reaction is investigated.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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